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張勇
（贛南師範大學化學化工學院副院長）
鎖定
張勇人物經歷
2003-2007，贛南師範大學應用化學專業，獲學士學位；
2007-2012，蘭州大學功能有機分子化學國家重點實驗室有機化學專業，獲博士學位，導師：王為教授（傑青、長江、重點實驗室主任）。
2012-至今，贛南師範大學，碩士生導師，副院長，應用化學系主任、黨支部書記。
張勇研究方向
張勇主要成就
論文：
[25]Cao,X.-M.; Zhang, A.-Y.; Cui,W.-R.; Liu, L.-Y.; Zhang, Y.-X.; Lin, H.*;Zhang, Y.* Azo-Linked Porous Polycalix[n]arenes forthe Efficient Removal of Organic Micropollutants from Water, ACSAppl. Mater. Interfaces, 2024, 16, 957−965.
[24]Cao,X.-M.; Liu, L.-Y.; Peng, Y.-X.; Wang, A.-J.;Zhang, A.-Y.; Ding, S.-Y.*; Lin, H.; Zhang,Y.* Natural Ellagic Acid-Derived Nanoporous Organic Polymersfor CO2 and Organic Dye Adsorption, ACS Appl. NanoMater., 2023, 6, 12330−12337.
[23]Huang, X.-Q.; Hong, X.; Lin, H.; Cao, X.-M.;Dang, Q.; Tang, S.-B.; Chen, D.-L.; Zhang, Y.*Hypercrosslinked Triazine-phloroglucinol Hierarchical PorousPolymers for the Effective Removal of Organic Micropollutants,Chem. Eng. J., 2022,90, 134990.
[22]Zhang, Y.*; Lai, G.-W.; Nie,L.-J.; He, Q.; Lin, M.-J.; Chi, R.; Lu, D.-L.*; Fan, X.*Organocatalytic difluorobenzylation of 1,2-diketones via mildcleavage of carbon–carbon bonds, Org. Chem. Front.,2022,9, 745−751.
[21]Zhang, Y.*;Hong, X.; Cao,X.-M.; Huang, X.-Q.; Hu, B.; Ding, S.-Y.; Lin, H.* Functionalporous organic polymers with conjugated triaryl triazine as thecore for superfast adsorption removal of organic dyes, ACSAppl. Mater. Interfaces, 2021,13,6359−6366.
[20]Li, X.; Sun, K.; Shen, W.; Zhang, Y.;Lu, M.-Z.; Luo, X.; Luo, H.-Q.* Rhodium(III)-Catalyzed DirectC−H Arylation of Various Acyclic Enamides with Arylsilanes,Org. Lett.,2021,23,31−36.
[19]Zhang, Y.* #;Hu,B.#; Cao, X.-M.; Luo, L.; Xiong, Y.; Wang, Z.-P.;Hong, X.; Ding, S.-Y.* -Cyclodextrinpolymer networks stabilized gold nanoparticle with superiorcatalytic activities, Nano Res., 2021,14,1018−1025.
[18]Zhang, Y.*;Ge, J.; Luo, L.; Yan S.-Q.; Lai,G.-W.; Mei, Z.-Q.; Luo, H.-Q.; Fan, X.-L.Difluoroisoxazolacetophenone: A Difluoroalkylation Reagent forOrganocatalytic Vinylogous Nitroaldol Reactions of 1,2-Diketones,Org. Lett.,2020,22,7952−7957.
[17]Zhang, Y.*;Nie, L.-J.; Luo, L.; Mao, J.-X.;Liu, J.-X.; Xu, G.-H.; Chen, D.; Luo, H.-Q.* Theselective condensation of pyrazolones to isatins in aqueousmedium, Tetrahedron,2020,76,130916.
[16]Luo, L.; Cao, X.-M.; Lai, G.-W.; Liu, J.-X.; Luo, H.-Q.; Lu,D.-L.; Zhang, Y.*“On Water” NucleophilicAddition of Pyrazolones to Trifluoromethyl Ketones, Chin. J.Org. Chem.,2020,40,1323−1330.
[15]Zhang, Y.*; Luo, L.; Ge, J.; Yan,S.-Q.;Peng,Y.-X.; Liu, Y.-R.; Liu, J.-X.;Liu, C.*; Ma, T.*; Luo, H.-Q. “On water” directorganocatalytic cyanoarylmethylation of isatins for thediastereoselective synthesis of 3-hydroxy-3-cyanomethyloxindoles, J. Org. Chem.,2019,84, 4000−4008.
[14]Zhang, Y.#;Xiong, Y.#;Ge, J.; Lin, R.; Chen, C.; Peng, Q.; Wang, D.-S.*; Li, Y.-D.Porous organic cage stabilised palladiumnanoparticles: efficientheterogeneous catalysts for carbonylation reaction of arylhalides, Chem. Commun.,2018,54,2796−2799.
[13]Han, M.-Y.*; Lin, J.; Li, W.; Luan, W.-Y.; Mai, P.-L.;Zhang, Y. Catalyst-free nucleophilic addition reactions ofsilyl glyoxylates in water, Green Chem., 2018, 20,1228−1232.
[12]Zhang, Y.*;Wang, Y.-P.; Ge, J.; Lai, G.-W.;Lu, D.-L.; Liu, J.-X.; Li, X.* ‘Base-catalyzed cascade1,6-sulfur-Michael/Henry reaction of trifluoromethyl-substitutedstyrylisoxazoles: Diastereoselective synthesis oftetrahydrothiophenes with a trifluoromethylated quaternarycenter, TetrahedronLett.,2018,59,941−944.
[11]Zhang, Y.*;Wei, B.-W.; Wang, W.-X.; Deng,L.-L.; Nie, L.-J.; Luo, H.-Q.; Fan, X.-L. Direct vinylogousoxidative cross-dehydrogenative coupling of 4-nitroisoxazoleswith N-aryltetrahydroisoquinolines in water under air conditions,RSC Adv.,2017,7,1229−1232.
[10]Zhang, Y.*;Wei, B.-W.; Zou, L.-N.; Kang,M.-L.; Luo, H.-Q.; Fan, X.-L.* ‘On water’ direct vinylogousHenry (nitroaldol) reactions of 3,5-dimethyl-4-nitroisoxazolewith aldehydes and trifluoromethyl ketones, Tetrahedron,2016,72,2472−2475.
[9]Zhang, Y.*;Wei, B.-W.; Lin, H.; Cui, W.-R.;Zeng, X.-Q.; Fan, X.-L.* Organocatalyzed Asymmetric VinylogousMichael Reactions of 3,5-Dialkyl-Substituted 4-Nitroisoxazoles: ADirect Method for the Synthesis of Chiral Isoxazole Derivatives,Adv. Synth. Catal.,2015,357,1299−1304.
[8]Zhang, Y.*;Wei,B.-W.; Lin, H.; Zhang, L.; Liu, J.-X.; Luo, H.-Q.; Fan, X.-L.*“On water” direct catalytic vinylogous Henry(nitroaldol) reactions of isatins for the efficient synthesis ofisoxazole substituted 3-hydroxyindolin-2-ones, Green Chem.,2015, 17, 3266−3270.
[7]Han, M.-Y.; Zhang,Y.; Wang, H.-Z.; An, W.-K.; Ma,B.-C.; Zhang, Y.; Wang, W.* Organocatalytic Michael Addition ofNitro Esters to -UnsaturatedAldehydes: Towards the Enantioselective Synthesis oftrans-3-Substituted Proline Derivatives, Adv.Synth. Catal.,2012,354,2635−2640.
[6]Zhu, J.-L.; Zhang,Y.;Liu, C.; Zheng, A.-M.; Wang, W.*Insights into the Dual Activation Mechanism InvolvingBifunctional Cinchona Alkaloid Thiourea Organocatalysts: An NMRand DFT Study, J. Org. Chem.,2012,77,9813−9825.
[5]Zhang, Y.; Wang, W.* Recent Advances inOrganocatalytic asymmetric Michael Reactions, Catal. Sci.Technol., 2012,2,42−53.
[4]Zhang, Y.; Zhang,Y.; Sun, Y.-L.; Du, X.; Shi, J.-Y.;Wang, W.-D.; Wang, W.*4-N,N-Dimethyl-aminopyridine-EmbeddedNanoporous Conjugated Polymer as Highly Active HeterogeneousOrganocatalyst, Chem. Eur. J.,2012, 18,6328−6334.
[3]Zhang, Y.;Shao, Y.-L.; Xu, H.-S.; Wang, W.*Organocatalytic Direct Asymmetric Vinylogous Michael Reaction ofan -Unsaturated-Butyrolactamwith Enone, J. Org. Chem.,2011,76,1472−1474.
[2]Zhang, Y.;Li, Z.-J.; Xu, H.-S.; Zhang, Y.; Wang,W.* Organocatalytic asymmetric Henryreaction of isatins: Highly enantioselective synthesis of3-hydroxy-2-oxindoles, RSC. Adv.,2011,1, 389−392.
[1]Zhu, N.; Ma, B.-C.; Zhang, Y.;Wang, W.* Organocatalyzed Highly Enantioselective andanti-Selective Construction of -Butenolidesthrough Vinylogous Mukaiyama Aldol Reaction, Adv. Synth.Catal.,2010, 352, 1291−1295.
參與著作：
[1]Zhang, Y.; Wang, W., C−C Bond Formation by MichaelReaction, Stereoselective Organocatalysis: Bond FormationMethodologies and Activation Modes, Rios, R. Ed., JohnWiley & Sons, Inc., 2013, Chapter 5, p147-204.
授權專利：
[1]張勇，聶隆駿，劉金香，範小林.一種含吡唑啉酮取代-3-羥基氧化吲哚衍生物及製備方法。專利號：ZL201910574545.6
張勇科研成果
1.新型手性有機分子籠的設計、合成及催化應用研究，國家自然科學基金青年基金項目（21502021），主持。
2.基於分子籠骨架有機多孔材料的製備及其應用研究，國家自然科學基金地區基金項目（21865003），主持。
3.“Bottom-up”策略構築金屬納米粒子-多孔有機聚合物，國家自然科學基金地區基金項目（22261003），主持。
4.分子籠基聚合物穩定超細金屬納米粒子的可控合成及其催化應用，江西省自然科學基金傑出青年基金項目（20232ACB213007），主持。
5. 手性多元雜環化合物的設計合成及其抗血吸蟲活性研究,江西省青年科學基金項目（20192BAB213007），主持。
6. 有機催化不飽和-丁內酰胺的不對稱合成研究,省教育廳青年科學基金項目（GJJ13655），主持。
張勇課程教學
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