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黃漢民

(中國科學技術大學教授)

鎖定
黃漢民,男,1974年6月生於湖北浠水,博士,中國科學技術大學教授、博士生導師,英國皇家化學會會士(RSC-Fellow),中科院特聘研究員。
中文名
黃漢民
出生地
湖北浠水
出生日期
1974年6月
畢業院校
中科院大連化學物理研究所
學位/學歷
博士
職    業
教師
專業方向
金屬有機化學,均相催化,不對稱催化
職    務
中國科學技術大學博士生導師
任職院校
中國科學技術大學
職    稱
中國科學技術大學教授

黃漢民人物經歷

2003年於中科院大連化學物理研究所獲得有機化學博士學位,
2004年至2008年在日本名古屋大學作JSPS博士後研究。
2008年4月到2016年3月在中國科學院蘭州化學物理研究所工作,先後任羰基合成與選擇氧化國家重點實驗室副主任和常務副主任。
2016年3月調入中國科學技術大學化學系工作。 [1] 

黃漢民科研成果

作為第一作者或通訊作者已發表研究論文90多篇,其中JACS(8篇),ACIE(9篇),Chem.Rev(1篇)和Chem.Soc.Rev.(1篇),被引用3000多次。相關研究工作分別被Chemical & Engineering News、Nature Chemical Biology、Synform和Synfacts作為亮點評述。曾獲國家自然科學基金優秀青年基金項目資助(2012),入選科技部中青年科技創新領軍人才(2015),國家萬人計劃領軍人才(2017),中國均相催化委員會均相催化青年獎(2013)和中科院優秀研究生指導教師獎(2015),指導的博士研究生多人次獲得研究生國家獎和中科院院長獎,一人獲得中科院優秀博士論文獎。目前主要研究領域為過渡金屬催化的合成方法及應用研究,着重發展惰性C-H和C-N鍵活化新策略,在此基礎上建立烴類物質和資源小分子高效轉化的新反應。 [1] 

黃漢民研究方向

1、金屬有機化學
2、均相催化
3、不對稱催化 [1] 

黃漢民論文專著

(1) Enantioselective Aminomethylamination of Conjugated Dienes with Aminals Enabled by Chiral Palladium Complex-Catalyzed C-N Bond Activation - J. Am. Chem. Soc. - 2016 - 2016, 138, 4314-4317.
(2) Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation - J. Am. Chem. Soc. - 2015 - 2015, 137, 12490-12493.
(3) Palladium-Catalyzed Dearomative Cyclocarbonylation via C-N Bond Activation - Angew. Chem. Int. Ed. - 2015 - 2015, 54, 10912-10916.
(4) Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome Basicity-Barrier Imparted by Aliphatic Amines - Angew. Chem. Int. Ed. - 2015 - 2015, 54, 7657-7661.
(5) Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN - Angew. Chem. Int. Ed. - 2015 - 2015, 54, 5900-5904.
(6) alladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes via C-N Bond Activation - Angew. Chem. Int. Ed. - 2014 - 2014, 53, 7272-7276.
(7) Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols - J. Am. Chem. Soc. - 2013 - 2013, 135, 18327-18330
(8) An Efficient Rh/O2 Catalytic System for Oxidative C-H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen - J. Am. Chem. Soc. - - 2013, 135, 8850-8853.
(9) Palladium-Catalyzed Oxidative Carbonylation of Benzylic C-H Bonds via Nondirected C(sp3)-H Activation. - J. Am. Chem. Soc. - - 2012, 134, 9902.
(10) A Highly Diastereo- and Enantioselective Reaction for Constructing Functionalized Cyclohexanes: Six Contiguous Stereocenters in one Step - Angew. Chem. Int. Ed. - - 2012, 51, 1248-1251.
(11) Enantioselective N-H Functionalization of Indole with α,β-Unsaturated γ-Lactams Catalyzed by Brønsted Acids - Angew. Chem. Int. Ed. - - 2011, 50, 5682-5686.
(12) Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C-H Bond Activation - J. Am. Chem. Soc. - - 2010, 132, 3650-3651.
(13) Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy to Construct Allylamines. - J. Am. Chem. Soc. - - 2012, 134, 20613-20616.
(14) Diastereo- and Enantioselective Catalytic Tandem Michael Addition/Mannich Reaction: Access to Chiral Isoindolinones and Azetidines with Multiple Stereocenters - Angew. Chem. Int. Ed. - - 2010, 49, 2728-2731.
(15) Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp2N/sp3N hybrid Ligands R-BINAN-R΄-Py - J. Am. Chem. Soc. - - 2006, 128, 8716-8717.
(16) Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C-H Bond Activation - Organometallics - 2016 - 2016
(17) Transition-Metal Catalyzed Redox-Neutral and Redox-Green C−H Bond Functionalization - The Chemical Record - 2016 - 2016
(18) Catalytic nucleophilic addition of alkynic C–H bond to α,β-unsaturated-γ-lactams - Chin. J. Catal. - 2016 - 2016
(19) Copper-catalyzed decarboxylative cross-coupling of cinnamic acids and ACCN via single electron transfer - Org. Biomol. Chem. - 2016 - 2016, 14, 2399-2402.
(20) Transition-Metal-Catalysed C-N Bond Activation - Chem. Soc. Rev. - 2016 - 2016, 45, 1257-1272.
(21) Palladium-Catalysed Coupling Reaction of Aminals with N-Sulfonyl Hydrazones to Give Allylic Sulfones - Org. Chem. Front. - 2016 - 2016, 3, 259-267
(22) Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines Promoted by Weak Acid - Tetrahedron Letters - 2016 - 2016, 57, 383-386.
(23) Decarboxylative Alkylcarboxylation of α,β-unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling - Org. Lett. - 2015 - 2015, 17, 4968-4971.
(24) Catalytic Nucleophilic Addition of Olefinic C-H Bond to α,β-Unsaturated-γ-Lactams - Tetrahedron Letters - 2015 - 2015, 57, 5533-5536.
(25) Lewis acid-catalyzed Difunctionalization of Enol Ethers with Aminals and Alcohols to β-Amino Acetals - Journal of Molecular Catalysis (China) - 2015 - 2015, 29(2), 103-110.
(26) Copper-Catalyzed Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds - ACS Catal. - 2015 - 2015, 5, 2882-2885.
(27) Transition-Metal-Catalyzed Direct Addition of Unactivated C−H Bonds to Polar Unsaturated Bonds - Chem. Rev. - 2015 - 2015, 115(9), 3468-3517.
(28) Diboron as Reductant for Nickel-Catalyzed Reductive Coupling: Rational Design and Mechanistic Studies - Chem. Comm. - 2015 - 2015, 51, 1850-1853.
(29) Iron-Catalyzed Alkenylation of Isochroman Acetals with Simple Alkenes - ChemCatChem - 2015 - 2015, 7, 250-253.
(30) Diastereo- and enantioselective conjugate addition of α-keto esters to nitroalkenes:Complete switch in the enantioselectivity by tuning the metal center or rigidity of the ligand - Chin. J. Catal. - 2015 - 2015, 36(1), 57-67.
(31) Palladium-catalyzed carbonylation of allylamines via C−N bond activation leading to β,γ-unsaturated amides - RSC Adv. - 2014 - 2014, 4(109), 64235-64237.
(32) Palladium-Catalyzed Direct Amination of Allylic Alcohols at Room Temperature - Synlett. - 2014 - 2014, 25(19), 2781-2786.
(33) A water Promoted-PBM protocol for Synthesize Tertiary Amines with Arylboronic Acids, Paraformaldehyde and Secondary Amines - J. Molecular Catal. - 2014 - 2014, 28, 197.
(34) Highly Enantioselective Hydrogenation of Steric Hindrance Enones Catalyzed by Ru-Complexes with Chiral Diamine and Achiral Phosphane - Org. Lett. - 2014 - 2014, 16, 3912-3915.
(35) Palladium-Catalyzed Intramolecular Oxidative C−H Sulfuration of Aryl Thiocarbamates - Adv. Synth. Catal. - 2014 - 2014, 356. 11-12,2471-2476.
(36) Rh-Catalyzed Oxidative C-H Activation/Annulation: Converting Anilines to Indoles with Molecular Oxygen as Sole Oxidant - Chem. Comm. - 2014 - 2014, 50, 4331-4334.
(37) An Efficient Rh/O2 Catalytic System for Oxidative Heck Reaction of Indoles and Alkenes via C–H Functionalization - Adv. Synth. Catal. - 2014 - 2014, 356. 1509-1515.
(38) Catalytic Cross Deoxygenative and Dehydrogenative Coupling of Aldehydes and Alkenes: Redox-Neutral Process to Skipped Dienes - Chem. Comm - - 2013, 49, 9839-9841.
(39) Palladium-Catalyzed Oxidative Aminocarbonylation: A New Entry to Amides via C-H Activation - Org. Lett. - - 2013, 15, 3370-3373.
(40) Copper-catalyzed oxidative amidation of dibenzylamines via C-H bond activation - Chin. J. Catal. - - 2013, 34(9), 1644-1650
(41) Copper-Catalyzed Aerobic Oxidative Amination of Arylboronic Acid with Aminal under Base-Free Conditions - Tetrahedron Letters - - 2013, 54, 2713.
(42) A Ruthenium Catalyst with Simple Triphenylphosphane for Enantioselective Hydrogenation of Aromatic Ketones - ChemCatChem - - 2013, 5, 2253-2257
(43) Cooperative Catalysis with Aldehyde and Copper: Development and Application in Aerobic Oxidative C-H Amination at Room Temperature. - Adv. Synth. Catal. - - 2013, 355, 1315.(Cover Pictur)
(44) Cu-Catalyzed Direct C-H Amination of 2-Alkylazaarenes with Azodicarboxylates via Nucleophilic Addition - Tetrahedron Letters - - 2013, 54, 711-714.
(45) Lewis Acid-Catalyzed Conjugate Addition of sp3C-H Bonds to Ethylidene Malononitriles. - Adv. Synth. Catal. - - 2012, 354, 2146-2150.
(46) Brønsted Acid Enhanced Rhodium-Catalyzed Conjugate Addition of Aryl C-H Bonds to α,β-Unsaturated Ketones under Mild Conditions - Chem. Eur. J. - - 2012, 18, 9511-9515.
(47) Asymmetric Catalytic Carbon-Carbon Bond Coupling Reactions via C-H Bond Activation, - Catal. Sci. Technol. - - 2012, 2(6), 1099-1112.
(48) Palladium-Catalyzed Selective C-H Benzylation towards Functionalized Azoles with Quaternary Carbon Center - Adv. Synth. Catal. - - 2012, 354, 1692-1700.
(49) Stereoselective Synthesis of trans <beta>-Lactams via Palladium/N-Heterocyclic Carbene-Catalyzed Carbonylative [2+2] Cycloaddition - Tetrahedron Letters - - 2012, 53, 1613-1616.
(50) Highly Diastereo- and Enantioselective Tandem Reaction toward Functionalized Pyrrolidines with Multiple Stereocenters - Org. Lett. - - 2011, 13, 5596-5599.
(51) Chiral Phosphoric Acid Catalyzed Enantioselective Aza-Michael Addition of Aromatic Amines to Nitroolefins - Chin. J. Catal. - - 2011, 32, 1573-1576.
(52) Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones - Chem. Eur. J. - - 2011, 17, 7760-7763.
(53) Readily Available and Recoverable Chiral Ionic Phosphite Ligands for the Highly Enantioselective Hydrogenation of Functionalized Olefins - Tetrahedron: Asymmetry - - 2011, 22, 769-774.
(54) Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation - Org. Lett. - - 2011, 13, 2580-2583.
(55) Copper-Catalyzed Oxidative Amination of Benzoxazoles via C-H and C-N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources - Org. Lett. - - 2011, 13, 522-525.
(56) Asymmetric Diels-Alder reaction catalyzed by Chiral Cyclic diamines - Journal of Molecular Catalysis (China) - - 2011, 25, 6-10.
(57) The Research Progress on the Grubbs-catalysts - Journal of Molecular Catalysis (China) - - 2011, 26, 566-575.
(58) Lewis Acid-Catalyzed C-H Functionalization for Synthesis of Isoindolinones and Isoindolines - Adv. Synth. Catal. - - 2010, 352, 3195-3200.
(59) Chiral Bronsted Acid Directed Iron-Catalyzed Enantioselective Friedel-Crafts Alkylation of Indoles with β-Aryl α’-Hydroxy Enones - Chem. Eur. J. - - 2010, 16, 1638-1645
(60) An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes - Org. Lett. - - 2009, 11, 4536.
(61) Design and Synthesis of New Chiral Pyridine-Phosphite Ligands for the Copper-Catalyzed Enantioselective Conjugate Addition of Diethylzinc to Acyclic Enones - Tetrahedron: Asymmetry - - 2009, 20, 1425-1432
(62) FeCl3-Catalyzed Addition of Et2Zn to Aldehydes - Journal of Molecular Catalysis (China) - - 2009, 23(6), 488-492.
(63) Rhodium-Catalyzed enantioselective Hydrogenation of β-Phthalimide Acrylates to Synthesis of β2-Amino Acids - Org. Lett. - - 2006, 8, 3359-3362
(64) Monophosphite Ligands Derived from Carbohydrates and H8-BINOL: Highly Enantioselective Rh-Catalyzed Asymmetric Hydrogenations - Tetrahedron: Asymmetry - - 2005, 16, 693-697.
(65) Carbohydrate-Drived Monophosphite ligands for Rh-Catalyzed Enantioselective Hydrogenation of α- and β-Dehydroamino Acid Esters - Tetrahedron: Asymmetry - - 2004, 15, 2011-2019
(66) A Novel Class of P-O Monophosphite Ligands Derived from d-Mannitol: Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations - J. Org. Chem. - - 2004, 69, 2355-2361.
(67) Structure Probing of D-Fructose Derived Ligands for Asymmetric Addition of Diethylzinc to Aldehydes - Tetrahedron: Asymmetry - - 2003, 14, 297-304
(68) Readily available new pyridyl alcohols derived from D-glucose as ligands for the enantioselective addition of diethylzinc to aldehydes - Tetrahedron Letters - - 2003, 14, 1285-1289.
(69) Chiral Monophosphites Derived from Carbohydrate: Conformational Effect in Catalytic Asymmetric Hydrogenation - Org. Lett. - - 2003, 5, 4137-4139.
(70) Synthesis of 3,3&#900;-Diaryl-Substituted 2,2&#900;-Diamino-1,1&#900;-binaphthyl and Its Derivatives, - J. Org. Chem. - - 2010, 75, 4315-4318.
(71) Study on the synthesis and absolute configurations of novel chiral ligands derived from D-glucose by 2D NMR - Chinese Journal of Magnetic Resonance - - 2003, 20, 271-275.
(72) Chiral organic catalysts and their applications in catalytic asymmetric reactions, Chinese Journal of Molecular Catalysis,2003, 17, 389-399. - - -
(73) Synthesis of monodentate phosphite ligands derived from carbohydrates and H8-BINOL and their application in Rh-catalyzed asymmetric hydrogenation of &#61537;-dehydroamino acids. Chinese Journal of Molecular Catalysis, 2005, 19(5), 388-393. - - -
(74) A novel synthesis of substituted phenylpyruvic acid by double carbonylation using cobalt pyridine-2-carboxylate catalyst. Synthetic Communications, 2000, 30, 3585-3588. - - -
(75) Double carbonylation of benzyl chloride to substituted phenylpyruvic acid catalyzed by cobalt pyridine-2-carboxylate. Chemical Journal of Chinese Universities, 2000, 21, 286-288. - - -
(76) Carbonylation of benzyl chloride to phenylacetic acid catalyzed by cobalt pyridine-2-carboxylate, Chinese Journal of fuel Chemistry and Technology, 2000, 28, 284-286. - - -
(77) One pot formation of catalytic and double carbonylation of benzyl chloride, J. Mol. Cata. (A-Chemical), 2003, 193(1-2), 97-102. - - -
(78) Five-membered Heterocycles, in Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis, Ed: Jean Rodriguez, and Damien Bonne, Wiley, 2015. - - -
(79) Chiral phosphorous ligands derived from D-mannitol: synthesis and their applications in asymmetric catalysis, in Mannitol: Chemistry, Uses and Potential Side Effects, Nova Science Publishers Inc., 2013. - - -
(80) Pd-Catalyzed Synthesis of Nitrogen-Containing Heterocycles, in Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation. Ed. Xiao-Feng Wu, Wiley-VCH 2016. - - - [1] 

黃漢民人物榮譽

2019年8月2日,黃漢民入選2019年度國家傑出青年科學基金建議資助項目申請人名單。 [2] 
參考資料