高戈

簡 歷

1994年9月 ~ 1998年7月，四川大學化學系，本科

1998年9月 ~ 2004年7月，四川大學化學系，博士研究生

2004年7月 ~ 2005年2月，四川大學化學學院，工作

2005年3月 ~ 2008年5月，美國University of Virginia，博士後

2008年7月 ~ ，四川大學化學學院，任教

主要研究方向

1、芳雜環構築熒光功能材料及應用

2、氟硼類熒光功能材料的合成與應用

3、有機合成方法學

主要工作業績

1、入選2013年教育部“新世紀優秀人才支持計劃”。

2、“簡單金屬鹽催化的C-C鍵和C-N鍵形成反應”，教育部自然科學獎一等獎，2011年1月，第6完成人。

3、 論文Angew. Chem. Inter. Ed.2006, 45(1), 122-125榮獲第一屆“中國百篇最具影響優秀國際學術論文”。 ^[1] 

代表性成果 （獲獎成果、專著、論文、專利）

1. He, Z.; Qi, X.; Li, S.; Zhao, Y.;Gao, G.;* Lan, Y.;* Wu, Y.; Lan, J.; You, J.*Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: A Simple Access to 1,3-DiketonesAngew. Chem. Int. Ed.2015, 54, 855.

2. Li, J.; Wang, Z.; Wu, N.; Gao, G.*You, J.* Radical Cascade Cyanomethylation of Activated Alkenes to Construct Cyano Substituted OxindolesChem. Commun.,2014, 50 (95), 15049.

3. Li,C.; Gao,C.; Lan,J.;You,J.;Gao,G.* An AIE Active Y-shaped Diimidazolylbenzene: Aggregation and Disaggregation for Cd2+ and Fe3+ Sensing in Aqueous SolutionOrg. Bio. Chem., 2014, 12, 9524.

4. Gao, C.; Gao, G.;* Lan, J.; You, J.* An AIE Active MonoimidazoliumSkeleton: High Selectivity and Fluorescence Turn-on for H2PO4- in Acetonitrile and ClO4- in WaterChem. Commun.2014,50, 5623.

5. Li, S.; Yang, F.; Lv, T.; Lan, J.; Gao, G.;* You, J.* Synthesis of Unsymmetrical Imidazolium Salts by Direct Quaternization of N-Substituted Imidazoles with Arylboronic AcidsChem. Commun.2014, 50, 3941.

6. Zhou, H.; Zhao, Y.; Gao, G.;* Li, S.; Lan, J.; You, J.* Highly Selective Fluorescent Recognition of Sulfate in Water by Two Rigid TetrakisimidazoliumMacrocycles with Peripheral ChainsJ. Am. Chem. Soc.2013, 135, 14908.

7. Lv, T.; Yang, L.; Zhao, Y.; Song, F.; Lan, J.; You, J.;* Gao, G.* One-pot Synthesis of Diarylimidazolium Salts from 1H-ImidazoleChin. Chem. Lett.2013, 24, 773.

8. 王志，周紅軍，胡俊毅，遊勁松*，高戈* 十字架型間二咪唑（鎓）苯的合成及對有機酸的識別化學學報2013, 71, 1257.

9. Hu, J.; He, Z.; Wang, Z.; Li, X.; You, J.; Gao, G.* A Simple Approach to Aggregation-Induced Emission in DifluoroboronDibenzoylmethane DerivativesTetrahedron Lett.2013, 54, 4167.

10. Lv, T.; Wang, Z.; You, J.* Lan, J.; Gao, G.;* Copper-Catalyzed Direct Aryl Quaternization of N-Substituted Imidazoles to Form Imidazolium SaltsJ. Org. Chem.2013, 78, 5723. ^[2] 

11. Zhou, H.; Wang, Z.; Gao, C.; You, J.; Gao, G.* Synthesis and Characterization of a Luminescent and Fully Rigid TetrakisimidazoliumMacrocycleChem. Commun.2013, 49, 1832.

12. Gao, C.; Zhou, H.; Wei, S.; Zhao, Y.; You, J.; Gao, G.* Novel Bisimidazolium Pincers as Low Loading Ligands for in situ Palladium-Catalyzed Suzuki-Miyaura Reaction in the Ambient AtmosphereChem. Commun.2013, 49, 1127.

13. 周紅軍，蘭靜波，高戈，遊勁松咪唑鎓大環的研究進展，中國科技論文2013, 8, 587.

14. Yang, S.; You, J.;* Lan, J.; Gao, G.* Facile Access to Extremely E?cient Energy-Transfer Pairs via an Unexpected Reaction of Squaraines with KetonesJ. Am. Chem. Soc.2012, 134, 11868.

15. Cheng, L.; Dong, J.; You, J.; Gao, G.;* Lan, J.* A Highly syn-Selective Nitroaldol Reaction Catalyzed by CuII-BisimidazolineChem. -Eur. J.2010, 16(23), 6761.

16. Gao, G.;* Pu, L.* γ-Hydroxy-α,β-acetylenic esters: asymmetric syntheses and applicationsSci China Chem.2010, 53, 21.

17. Gao, G.; Wang, Q.; Yu, X. -Q.*; Xie, R. -G.; Pu, L.*Highly Enantioselective Synthesis of γ-Hydroxy-α,β-acetylenic Esters by Asymmetric Alkyne Addition to AldehydesAngew. Chem. Int. Ed.2006, 45(1), 122.

18. Gao, G.; Xie, R. -G.; Pu, L.*Highly Enantioselective Alkyne Additions to Aldehydes in the Presence of BINOL and HMPAProc. Natl. Acad. Sci. USA2004, 101(15), 5417.

19. Gao, G.; Moore, D.; Xie, R. -G.; Pu, L.*Highly Enantioselective Phenylacetylene Additions to Both Aliphatic and Aromatic AldehydesOrg. Lett.2002, 4(23), 4143.

20. Gao, G.; Xiao, R.; Yuan, Y.; Zhou, C. -H.; You,J. -S.;Xie,R. -G.*Efficient Imidazolium Catalysts for the Benzoin CondensationJ. Chem. Res. -S.2002, (6), 262. ^[3]