高希珂

2005-09--2008-07 中國科學院化學研究所 博士

（ 1 ） 一種2,3,6,7-四溴代萘四羧酸二酰亞胺化合物、製備及用途, 發明, 2009, 第 1 作者, 專利號: ZL201210019769.9

（ 2 ） Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 發明, 2012, 第 1 作者, 專利號: US 8,471,021B2

（ 3 ） 硫雜環稠合的萘二酰亞胺類化合物、製備方法和應用, 發明, 2011, 第 1 作者, 專利號: ZL201110225678.6

（ 4 ） 含硒π擴展萘四羧酸二酰亞胺化合物、製法和應用, 發明, 2014, 第 1 作者, 專利號: 2014100407588

（ 5 ） Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 發明, 2010, 第 1 作者, 專利號: JP5416282

（ 6 ） 一鍋法制備硫雜環稠合的萘二酰亞胺衍生物的方法, 發明, 2011, 第 1 作者, 專利號: ZL201110224812.0

（ 7 ） Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 發明, 2012, 第 1 作者, 專利號: 10-1496931

（ 8 ） 含2-(1,3-二硫/硒-2-亞基)乙氰共軛結構單元的萘二酰亞胺及其衍生物, 發明, 2014, 第 1 作者, 專利號: ZL2014104222896

（ 9 ） 二噻吩並䓛二酰亞胺衍生物、其中間體、製備方法和應用, 發明, 2020, 第 1 作者, 專利號: 201710244321.X

（ 10 ） 含有1,3-二硫-2-葉立德烯共軛單元的萘二酰亞胺衍生物、製備方法和應用, 發明, 2013, 第 1 作者, 專利號: ZL201310322972.8

（ 11 ） 聯薁二酰亞胺衍生物、其製備方法和應用, 發明, 2019, 第 1 作者, 專利號: 201610554416.7

（ 12 ） 以萘四羧酸二酰亞胺為核的硫雜共軛化合物、製法和應用, 發明, 2009, 第 1 作者, 專利號: ZL200910197611.9

（ 13 ） 硫雜環稠合的萘四羧酸二酰亞胺衍生物及製法和應用, 發明, 2010, 第 1 作者, 專利號: ZL201010207565.9

（ 14 ） 一種含薁共軛聚合物、其中間體及應用, 發明, 2020, 第 1 作者, 專利號: 201711279898.0

（ 15 ） Sulfur Containing Heterocycle-Fused Naphthalene Tetracarboxylic Acid Diimide Derivatives, Preparation Method And Use Thereof, 發明, 2018, 第 1 作者, 專利號: EU2492271

1. Hanshen Xin, Bin Hou, Xike Gao.* Azulene-Based π‑Functional Materials: Design, Synthesis, and Applications. Acc. Chem. Res. 2021, 54 , 1737-1753.

2. Hanshen Xin, Jing Li, Ru-Qiang Lu, Xike Gao,* Timothy. M. Swager.* Azulene–Pyridine-Fused Heteroaromatics. J. Am. Chem. Soc. 2020, 142, 13598-13605.

3. Hanshen Xin, Congwu Ge, Xiaodi Yang, Honglei Gao, Xiaochun Yang, Xike Gao.* Biazulene diimides: a new building block for organic electronic materials. Chem. Sci. 2016, 7, 6701-6705. (Highlighted by Synfacts 2016, 12,1040)

4. Hanshen Xin, Congwu Ge, Xuechen Jiao, Xiaodi Yang, Kira Rundel, Christopher R. McNeill, Xike Gao.* Incorporation of 2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Towards High-Performance Organic Optoelectronic Materials. Angew. Chem. Int. Ed. 2018, 57, 1322-1326. (Highlighted by Synfacts 2018, 14, 0258 and Sci. China. Chem. 2018, 61, 973-974)

5. Hanshen Xin, Xike Gao.* Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog. ChemPlusChem. 2017, 82, 945-956. (Most accessed and cited paper, highlighted by Angew. Chem. Int. Ed. 2017, 56, 10018)

6. Yunbin Hu, Zhongli Wang, Xu Zhang, Xiaodi Yang, Congwu Ge, Lina Fu, Xike Gao.* A Class of Electron-Transporting Vinylogous Tetrathiafulvalenes Constructed by the Dimerization of Core-Expanded Naphthalenediimides. Org. Lett. 2017, 19, 468-471. (Highlighted by Synfacts 2017, 13, 0373)

7. Xueqian Zhao, Congwu Ge, Xiaodi Yang, Xike Gao.* Dithieno 3,2-a:3Dithieno[3,2-a:3’,2’-j][5,6,11,12]chrysene diimides and their Molecular Energy Levels Regulation. Mater. Chem. Front. 2017, 1, 1635-1640.

8. Honglei Gao, Congwu Ge, Bin Hou, Hanshen Xin, Xike Gao.* Incorporation of 1,3-Free-2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Improving Proton Responsiveness and Electrical Conductivity. ACS Macro Lett. 2019, 8, 1360-1364. (Highlighted by Synfacts 2019, 15,1374)

9. Xike Gao,* Chong-an Di,* Yunbin Hu, Xiaodi Yang, Hongyu Fan, Feng Zhang, Yunqi Liu, Hongxiang Li, Daoben Zhu. Core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups for high-performance, ambient-stable, solution-processed n-channel organic thin film transistors. J. Am. Chem. Soc. 2010, 132, 3697-3699.

10. Fengjiao Zhang,# Yunbin Hu,# Torben, Schuettfort, Chong-an Di,* Xike Gao,* Christopher R McNeill,* Lars Thomsen, Stefan C B Mannsfeld, Wei Yuan, Henning Sirringhaus, Daoben Zhu.* Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N-channel Organic Thin-film Transistors with Mobility of up to 3.50 cm²V^-1s^-1. J. Am. Chem. Soc. 2013, 135, 2338-2349. (# Co-first authors)

（1） Azulene-Based π‑Functional Materials: Design, Synthesis, and Applications, Accounts of Chemical Research, 2021, 通訊作者

（2） Azulene-Based BN-Heteroaromatics, The Journal of Organic Chemistry, 2020, 85(1): 70-78., 2020, 通訊作者

（3） 基於硫雜萘二酰亞胺的席夫鹼型聚合物電子傳輸材料基於硫雜萘二酰亞胺的席夫鹼型聚合物電子傳輸材料, 功能高分子學報 2020, 33(2): 148-156., 2020, 通訊作者

（4） Rhodanine-Bridged Core-Expanded Naphthalene Diimide Derivatives for n-Type Semiconductors, Organic Materials 2020, 2, 165–172, 2020, 通訊作者

（5） Azulene–Pyridine-Fused Heteroaromatics, Journal of the American Chemical Society, 2020, 通訊作者

（6） Incorporation of 1,3-Free-2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Improving Proton Responsiveness and Electrical Conductivity, ACS Macro Letterss, 2019, 8(10): 1360-1364. , 2019, 通訊作者

（7） Dithieno[3,2-a:3′,2′-j][5,6,11,12]chrysene diimides: a versatile electron-deficient building block for polymeric semiconductors, Chemical Communications , 2019, 55(69): 10234-10237., 2019, 通訊作者

（8） Enantiopure versus racemic naphthalene diimide-based n-type organic semiconductors: effect on charge transport, Journal of Materials Chemistry C, 2019, 7(9): 2659-2665., 2019, 通訊作者

（9） From Homochiral Assembly to Heterochiral Assembly: A Leap in Charge Transport Properties of Binaphthol-Based Axially Chiral Materials, Langmuir, 2019, 35(18): 6188-6195., 2019, 通訊作者

（10） Incorporation of 2,6-Connected Azulene Units into the Backbone of Conjugated Polymers: Towards High-Performance Organic Optoelectronic Materials., Angew. Chem. Int. Ed. 2018, 57, 1322-1326., 2018, 通訊作者

（11） 6,6'-Diaryl-Substituted Biazulene Diimides for Solution-Processable High-Performance n-Type Organic Semiconductors., Mater. Chem. Front., 2018,2, 975-985, 2018, 通訊作者

（12） The role of halogen bonding in improving OFET performance of a naphthalenediimide derivative., Chin. Chem. Lett. 2018, 29, 423-428., 2018, 通訊作者

（13） Photoresponsive n-channel organic field-effect transistors based on a tri-component active layer., Chin. Chem. Lett. 2018, 29, 175-178., 2018, 通訊作者

（14） A Class of Electron-Transporting Vinylogous Tetrathiafulvalenes Constructed by the Dimerization of Core-Expanded Naphthalenediimides., Organic Letters, 2017, 19(3): 468-471., 2017, 通訊作者

（15） Application of direct (hetero)arylation in constructing conjugated small molecules and polymers for organic optoelectronic devices., Tetrahedron. Lett., 2017, 通訊作者

（16） Synthesis of largely π-extended naphthalenediimides via C–H activation towards highly soluble and narrow band-gap organic optoelectronic materials., Org. Chem. Front., 2017, 通訊作者

（17） Naphthalene Diimides Endcapped with Ethynylazulene：Molecular Design, Synthesis and Properties., Chin. J. Org. Chem., 2017, 通訊作者

（18） Dithieno[3,2-a:3′,2′-j][5,6,11,12]chrysene diimides and their molecular energy level regulation, Mater. Chem. Front., 2017, 通訊作者

（19） Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog, ChemPlusChem., 2017, 通訊作者

（20） Incorporation of benzothiadiazole into the backbone of 1,2,5,6-naphthalenediimide based copolymers, enabling much improved film crystallinity and charge carrier mobility., Poly. Chem., 2016, 通訊作者

（21） Biazulene Diimides: A New Building Block for Organic Electronic Materials., Chem. Sci., 2016, 通訊作者

（22） Controlled Growth of Ultrathin Film of Organic Semiconductors by Balancing the Competitive Processes in Dip-Coating for Organic Transistors., Langmuir., 2016, 通訊作者

（23） Fine-tuning the molecular energy levels by incorporating thiophene units onto the p-backbone of core-expanded naphthalene diimides., Chin. Chem. Lett., 2016, 通訊作者

（24） Photoresponsive organic field-effect transistors involving photochromic molecules., Chin. Chem. Lett., 2016, 通訊作者

（25） N-Channel Organic Transistors Processed from Halogen-Free Solvents: Solvent Effect on Thin-Film Morphology and Charge Transport., Chin. J. Chem., 2016, 通訊作者

（26） Bismuth Interfacial Doping of Organic Small Molecules for High Performance n-type Thermoelectric Materials., Angew. Chem. Int. Ed., 2016, 第 7 作者

（27） Scanning Kelvin Probe Microscopy Investigation of the Roleof Minority Carriers on theSwitching Characteristics ofOrganic Field-Effect Transistors, Adv. Mater., 2016, 第 5 作者

（28） Carbazolo[2,1-a]carbazole Diimide: A Building Block for Organic Electronic Materials., ChemPlusChem., 2015, 通訊作者

（29） Synthesis of Monolateral and Bilateral Sulfur-Heterocycle Fused Naphthalene Diimides (NDI) from Monobromo and Dibromo NDIs., Org. Chem. Front., 2015, 通訊作者

（30） High mobility organic semiconductors for field-effect transistors., Sci. China. Chem., 2015, 通訊作者

（31） Modulated Thermoelectric Properties of Organic Semiconductors Using Field-Effect Transistors, Adv. Funct. Mater., 2015, 第 5 作者

（32） Flexible suspended gate organic thin-film transistors for ultra-sensitive pressure detection, Nat. Commun., 2015, 第 4 作者

（33） Naphthalene Diimides Fused with 2-(1,3-dithiol-2-ylidene)acetonitrile: Strong Electron-Deficient Building Blocks for High-Performance n-Type Polymeric Semiconductors., ACS Macro Lett., 2014, 通訊作者

（34） Specific and Reproducible Gas Sensors Utilizing Gas-phase Chemical Reaction on Organic Transistors, Adv. Mater., 2014, 通訊作者

（35） Development of n-Type Organic Semiconductors for Thin Film Transistors: A Viewpoint of Molecular Design., J. Mater. Chem. C, 2014, 通訊作者

（36） Tuning the Charge Transport Property of Naphthalene Diimide Derivatives by Changing the Substituted Position of Fluorine Atom on Molecular Backbone., Chin. J. Chem., 2014, 通訊作者

（37） Tetracyanodibenzotetrathiafulvalene Diimides: Design, Synthesis and Property Study., J. Org. Chem. , 2013, 通訊作者

（38） 1,2,5,6-Naphthalenediimides-Based Donor？Acceptor Copolymers Designed from Isomer Chemistry for Organic Semiconducting Materials., Macromolecules., 2013, 通訊作者

（39） New Core-Expanded Naphthalene Diimides for n-Channel Organic Thin Film Transistors., Chin. J. Chem. , 2013, 通訊作者

（40） A facile synthesis of 2,3,6,7-tetrabromonaphthalene diimides toward new π-extended naphthalene diimides., Tetrahedron Lett., 2013, 通訊作者

（41） Ultra-Thin Film Organic Transistors: Precise Control of Semiconductor Thickness via Spin-coating., Adv. Mater. , 2013, 通訊作者

（42） Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N-channel Organic Thin-film Transistors with Mobility of up to 3.50 cm2V-1s-1., J. Am. Chem. Soc., 2013, 通訊作者

（43） One-pot synthesis of core-expanded naphthalene diimides: enabling N-substituent modulation for diverse n-type organic materials. , Org. Lett. , 2012, 通訊作者

（44） All-Solution-Processed, High-Performance n-Channel Organic Transistors and Circuits: Toward Low-Cost Ambient Electronics, Adv. Mater. , 2011, 通訊作者

（45） Core-expanded naphthalene diimides fused with sulfur heterocycles and end-capped with electron-withdrawing groups for air-stable solution-processed n-channel organic thin film transistors. , Chem. Mater. , 2011, 通訊作者

（46） Core-expanded naphthalene diimides fused with 2-(1,3-dithiol-2-ylidene)malonitrile groups for high-performance, ambient-stable, solution-processed n-channel organic thin film transistors. , J. Am. Chem. Soc. , 2010, 通訊作者 ^[1]