反饋

蔡正國

（東華大學教授，博士生導師）

鎖定

蔡正國，出生於1975年05月17日，是東華大學教授，博士生導師。

中文名: 蔡正國
國籍: 中國
出生日期: 1975年05月17日

畢業院校: 吉林工學院
職業: 教師
性別: 男
職稱: 教授

蔡正國人物經歷

蔡正國，博士學位，現任東華大學材料科學與工程學院高分子科學與工程系教授，博士生導師。

主要經歷

1993. 9 - 1997. 7:吉林工學院，高分子材料，學士

2002. 9 - 2004. 7: 日本東京工業大學，高分子化學與物理，碩士（導師：Takeshi SHIONO）

2004. 9 - 2007. 3: 日本廣島大學，高分子化學與物理，博士（導師：Takeshi SHIONO）

2010. 8 - 2011.1: 美國芝加哥大學，訪問學者

2007. 4 - 2011: 日本廣島大學，助理教授

2011-東華大學材料科學與工程學院，教授

蔡正國研究方向

配位聚合與大分子設計；新型成纖高聚物設計、合成及應用研究。

蔡正國主要貢獻

主要論文

1.Cao, L.; Cai, Z.; Li, M., Phosphinobenzenamine NickelCatalyzed Efficient Copolymerization of Methyl Acrylate with Ethylene andNorbornene(2022) Macromolecules, 55 (9), 3513-3521.^[22]
2. Yuan, H.; Kida, T.; Tanaka, R.; Cai, Z.; Nakayama, Y.; Kihara, S.-i.; Shiono, T., Star polymers with norbornene/1-octenegradient copolymer arms synthesized by anansa-fluorenylamidodimethyltitanium-[Ph3C][B(C₆F₅)₄] catalyst system(2022) Polymer, 249, 124844.^[23]
3.Zhang, H., Zou, C., Zhao, H., Cai, Z., Chen, C.Hydrogen-Bonding-Induced Heterogenization of Nickel and Palladium Catalysts for Copolymerization of Ethylene with Polar Monomers(2021) Angewandte Chemie - International Edition, 60 (32), pp. 17446-17451.^[1]
4.Wang, Z., Shu, X., Zhang, H., Cao, L., Li, Y., Cai, Z.Synthesis of 1,2-bis(imidazolidin-2-imine)benzene nickel complexes and their application for norbornene (co)polymerization with styrene(2021) European Polymer Journal, 150^[2]
5.Yuan, H., Kida, T., Tanaka, R., Cai, Z., Nakayama, Y., Shiono, T.Erratum: Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using: Ansa-fluorenylamidodimethyltitanium-[Ph₃C][B(C₆F₅)₄] catalyst system (Polymer Chemistry (2021) DOI: 10.1039/d0py01370f)(2021) Polymer Chemistry, 12 (5), p. 771.^[3]
6.Zou, C., Zhang, H., Tan, C., Cai, Z.Polyolefins with Intrinsic Antimicrobial Properties(2021) Macromolecules, 54 (1), pp. 64-70.^[4]
7.Li, Y., Zhang, H., Xiao, R., Cai, Z.Bis(N-acylated imidazolin-2-imine) nickel catalyzed norbornene copolymerization with methyl acrylate(2020) Polymer Chemistry, 11 (34), pp. 5542-5547.^[5]
8.Li, Y.-Q., Zhou, J., Xiao, R., Cai, Z.-G.Quinolinyl Imidazolidin-2-imine Nickel Catalyzed Efficient Copolymerization of Norbornene with para-Chlorostyrene(2020) Chinese Journal of Polymer Science (English Edition), 38 (9), pp. 941-949.^[6]
9.Yuan, H., Kida, T., Kim, H., Tanaka, R., Cai, Z., Nakayama, Y., Shiono, T.Synthesis and Properties of Gradient Copolymers Composed of Norbornene and Higher α-Olefins Using an ansa-Fluorenylamidodimethyltitanium-[Ph₃C][B(C₆F₅)₄] Catalyst System(2020) Macromolecules, 53 (11), pp. 4323-4329.^[7]
10.Li, Y., Cheng, H., Xiao, R., Cai, Z.Rational design of nickel catalysts containing N-acylated imidazolin-2-imine ligand for ethylene copolymerization with polar monomer(2020) Journal of Catalysis, 383, pp. 117-123.^[8]
11.Sun, Y., Wang, C., Tanaka, R., Shiono, T., Cai, Z.Copolymerization of Ethylene and Fluoroalkylnorbornene Using Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts(2019) Macromolecular Chemistry and Physics, 220 (19), 1900306.^[9]
12.Li, M., Zhang, H., Cai, Z., Eisen, M.S.Norbornene polymerization and copolymerization with 1-alkenes by neutral palladium complexes bearing aryloxide imidazolin-2-imine ligand(2019) Polymer Chemistry, 10 (21), pp. 2741-2748.^[10]
13.Song, X., Cao, L., Tanaka, R., Shiono, T., Cai, Z.Optically Transparent Functional Polyolefin Elastomer with Excellent Mechanical and Thermal Properties(2019) ACS Macro Letters, 8 (3), pp. 299-303.^[11]
14.Tan, L.Y., Tsuchido, Y., Osakada, K., Cai, Z., Takahashi, Y., Takeuchi, D.Synthesis and Aggregation Behavior of Poly(arylene alkenylene)s and Poly(arylene alkylene)s Having Dialkoxyphenylene and Aromatic Diimide Groups(2019) Macromolecules, 52 (4), pp. 1642-1652.^[12]
15.Li, M., Cai, Z., Eisen, M.S.Neutral Nickel(II) Complexes Bearing Aryloxide Imidazolin-2-imine Ligands for Efficient Copolymerization of Norbornene and Polar Monomers(2018) Organometallics, 37 (24), pp. 4753-4762.^[13]
16.Ding, L., Cheng, H., Li, Y., Tanaka, R., Shiono, T., Cai, Z.Efficient ethylene copolymerization with polar monomers using palladium anilinonaphthoquinone catalysts(2018) Polymer Chemistry, 9 (45), pp. 5476-5482.^[14]
17.Cheng, H., Wang, H., Li, Y., Hu, Y., Zhang, X., Cai, Z.Structurally simple dinuclear nickel catalyzed olefin copolymerization with polar monomers(2018) Journal of Catalysis, 368, pp. 291-297.^[15]
18.Wang, H., Li, Y., Cai, Z.Substituent effects of phenyl group on silylene bridge in stereospecific polymerization of propylene with C1-symmetric ansa-silylene(fluorenyl)(amido) dimethyl titanium complexes(2018) Polymers, 10 (10).^[16]
19.Wang, H., Cheng, H., Tanaka, R., Shiono, T., Cai, Z.Efficient control of ethylene-norbornene copolymerization behavior of a fluorenylamido-ligated titanium complex: Substituent effects of the amido ligand and copolymer properties(2018) Polymer Chemistry, 9 (35), pp. 4492-4497.^[17]
20.Cheng, H., Su, Y., Hu, Y., Zhang, X., Cai, Z.Ethylene polymerization and copolymerization with polar monomers using nickel complexes bearing anilinobenzoic acid methyl ester ligand(2018) Polymers, 10 (7)^[18]
21.Li, M., Shu, X., Cai, Z., Eisen, M.S.Synthesis, Structures, and Norbornene Polymerization Behavior of Neutral Nickel(II) and Palladium(II) Complexes Bearing Aryloxide Imidazolidin-2-imine Ligands(2018) Organometallics, 37 (7), pp. 1172-1180.^[19]
22.Cheng, H., Cai, Z.(Anilino)anthraquinone Nickel-Catalyzed Random Copolymerization of Norbornene and Ethylene(2018) ChemCatChem, 10 (3), pp. 497-500.^[20]
23.Song, X.-Y., Ma, Q., Yuan, H.-B., Cai, Z.-G.Synthesis of hydroxy-functionalized ultrahigh molecular weight polyethylene using fluorenylamidotitanium complex(2018) Chinese Journal of Polymer Science (English Edition), 36 (2), pp. 171-175.^[21]