李國柱

李國柱：天津大學化工學院副教授

研究方向:

燃料化學與技術，多相催化

講授課程:化工過程控制，化工導論，Introduction to Chemical Engineering Thermodynamics

學術成就:

圍繞新型燃料的設計和合成展開了系統的研究。通過理論計算預測不同結構和組成燃料的性質，指導高密度燃料製備，優化得到的燃料體積熱值高、吸熱能力強、熱安定性好，性能優異；研究了仿生調控下納米貴金屬的構型同其活性的構效關係，通過調控表面構型提高了其加氫活性和選擇性；提出了一種醇基吸熱燃料的策略，研發了其有效技術途徑，相比於普通燃料其吸熱能力提高了10%以上、裂解結焦量降低了80%以上。對金屬銀在催化反應過程中表面重構的研究大幅提高了納米銀的催化活性，研究成果發表在催化領域頂級期刊“Journal of Catalysis”上，受到了審稿人的高度評價。對甲醇作為吸熱燃料的研究有效提高了燃料熱沉並大幅降低了結焦，成果發表在“Energy & Fuels”上。對貴金屬加氫催化劑的研究有效提高了其加氫活性，成果在J. Mater. Chem. A和Catal. Sci. Tech.上。 ^[1] 

科研項目:

仿生調控Pt/SBA-15的構型機制與催化加氫性能研究，國家自然科學基金青年基金（21306132）

催化加氫用Pt/SBA-15的仿生調控合成研究，教育部博士點新教師基金（20120032120008）

論著專利:

1 Guozhu Li,* Yujiao Jiang, Danlei Chen, Jian Li, Shuxiang Lu, Increased silver activity as a result of controllable reaction-driven reconstruction for high-index facets, Journal of Catalysis, 2014, 317, 83-90.

2 Yujiao Jiang, Guozhu Li,* Xiaodi Li, Shuxiang Lu,* Li Wang and Xiangwen Zhang, Water-dispersible Fe₃O₄ nanowires as efficient supports for noble-metal catalysed aqueous reactions, J. Mater. Chem. A, 2014, 2, 4779-4787

3 Qin Zhang, Guozhu Liu, Li Wang, Xiangwen Zhang, and Guozhu Li,* Controllable Decomposition of Methanol for Active Fuel Cooling Technology, Energy & Fuels, 2014, 28(7), 4431-4439.

4 Xiaodi Li, Guozhu Li,* Wanting Zang, Li Wang, Xiangwen Zhang, Catalytic activity of shaped platinum nanoparticles for hydrogenation: a kinetic study, Catalysis Science & Technology, 2014, 4, 3290-3297.

5 Rong Hu, Guozhu Li,* Jiang Y, et al. Silver–Zwitterion Organic–Inorganic Nanocomposite with Antimicrobial and Antiadhesive Capabilities. Langmuir, 2013, 29(11): 3773-3779.

6 Jiangge Hao, Ying Wang, Guozhu Liu, Jingwen Zhang, Guozhu Li,* Xuesong Ma, Synthesis of ITQ-2 Zeolites and Catalytic Performance in n-Dodecane Cracking, Chinese Journal of Chemical Engineering, 2014, published online.

7 Hongyu Chen, Yan Huang, Yanxiang Li, John A. Roper, III, Christopher J. Tucker, Gerald A. Vandezande, Yu Zhang, Guozhu Li, John Klier, Moisture curable compositions and low surface energy coating compositions made therefrom, US 20140088219 A1.

8 Guozhu Li, Gang Cheng, Hong Xue, Shengfu Chen, Fengbao Zhang, Shaoyi Jiang, ultra low fouling zwitterionic polymers with a biomimetic adhesive group, Biomaterials 2008, 29, 4592-4597.

9 Guozhu Li, Hong Xue, Changlu Gao, Fengbao Zhang, and Shaoyi Jiang, nonfouling polyampholytes from an ion-pair comonomer with biomimetic adhesive groups, Macromolecules 2010, 43, 14-16.

10 Changlu Gao, Guozhu Li (co-first author), Hong Xue, Wei Yang, Fengbao Zhang and Shaoyi Jiang, functionalizable and ultra low fouling zwitterionic surfaces via adhesive mussel mimetic linkages, Biomaterials 2010, 31, 1486-1492.

11 Guozhu Li, Hong Xue, Gang Cheng, Shengfu Chen, Fengbao Zhang, and Shaoyi Jiang, ultralow fouling zwitterionic polymers grafted from surfaces covered with an initiator via an adhesive mussel mimetic linkage, J. Phys. Chem. B 2008, 112, 15269-15274.

12 Guozhu Li, Xianyu Li, Wenchao Peng, Xiaobin Fan, Guoliang Zhang, Fengbao Zhang, synthesis of nearly monodisperse nanoparticles in alcohol: A pressure and solvent-induced low-temperature strategy, Applied Surface Science 2009, 255, 7021-7027.

13 Guozhu Li, Wenchao Peng, Xianyu Li, Xiaobin Fan, Guoliang Zhang, Fengbao Zhang, pressure and solvent induced low-temperature synthesis of monodisperse superparamagnetic nanocrystals: The case of Fe₃O₄ in alkanols, Applied Surface Science 2008 254, 4970-4979.

14 Nick Aldred, Guozhu Li, Ye Gao, Anthony S. Clare and Shaoyi Jiang, Modulation of barnacle (Amphibalanus amphitrite Darwin) cyprid settlement behavior by sulfobetaine and carboxybetaine methacrylate polymer coatings, Biofouling 2009, 26, 673-683.

15 Guozhu Li, Fengbao Zhang, Guoliang Zhang, Jian Han, Recovery of Na₂SO₄ from Remediation of Wastewater and Reuse for Preparation of Sodium 4-Nitrotoluene-2-sulfonate (NTSNa), Desalination 2006, 194, 176-181.

16 李國柱，張鳳寶，張國亮，賈春燕， 用氧化－絮凝法處理DSD酸還原廢水的實驗室及工業實驗，工業水處理 2005, 9, 30-33.

17 Gang Cheng, Guozhu Li, Shengfu Chen, Zheng Zhang, Shaoyi Jiang, zwitterionic carboxybetaine polymer surfaces and their resistance to long-term biofilm formation, Biomaterials 2009, 30, 5234-5240.

18 Gang Cheng, Hong Xue, Guozhu Li, Shaoyi Jiang, Integrated Antimicrobial and Nonfouling Hydrogels to Inhibit the Growth of Planktonic Bacterial Cells and Keep the Surface Clean, Langmuir 2010, 26, 10425-10428.

19 Xiaobin Fan, Fengbao Zhang, Guoliang Zhang, Guozhu Li, Kinetics and Mechanism Study on the Preparation of 4,4'-Diaminostilbene-2,2'-disulfonic Acid by Reduction of 4,4’-Dinitrostilbene-2,2’-disulfonic Acid with Zero-Valent Iron, Dyes and Pigments 2007, 75, 373-377.

20 張鳳寶，李國柱，張國亮，氧化/絮凝處理生產DSD酸過程中的還原廢水的方法，專利號 ZL 200410020218.X

Shaoyi Jiang, Changlu Gao, Guozhu Li, et al., Zwitterionic polymers having biomimetic adhesive linkages, US 2011/0105712 A ^[2]