於長江

2012年6月於安徽師範大學碩士研究生畢業後留校工作，2016年6月取得化學博士學位，2018年8月至2020年7月在香港理工大學應用生物與化學科技系做博士後研究。2022年12月，受聘副教授。目前主要從事新型有機功能染料的設計開發、性質及其在能源、材料、生物等領域的應用探索研究。期刊上發表論文32篇。

1) 多硼氮芳香稠環的合成、性質及應用

2) 異吲哚吡咯染料的合成、性質及應用

科研工作經歷：

2012.7 至 今，安徽師範大學，化學與材料科學學院，碩士生導師

2018.8-2020.7，香港理工大學，應用生物與化學科技系，Postdoctoral Fellow，合作導師：Prof. Wong, Wai-Yeung

學習教育經歷：

2013.9–2016.7，安徽師範大學，化學學科專業，博士，導師：焦莉娟 教授

2009.9–2012.6，安徽師範大學，有機化學專業，碩士，導師：焦莉娟 教授

2005.9–2009.7，安徽師範大學，應用化學專業，學士

1) 2023年度安徽省高校科研項目，2023AH050149，高穩定高亮近紅外二區雙並氟硼二叱咯的設計開發與性質研究，2023.9-2026.8，在研

2）安徽省博士後研究人員科研活動項目，2021B533，高性能雙硼肼橋聯水楊酰腙吡咯熒光團的合成、性質及應用研究，2021.11-2023.11，在研

3) 安徽省自然科學青年基金項目，2008085QB67，新型立體扭曲雙硼肼橋聯水楊酰腙吡咯熒光團的設計合成、光學性質及自組裝研究，2020.7-2022.6，已結題

4) 南京大學配位化學國家重點實驗室開放基金，SKLCC1911，近紅外二區AIE 型苯並四吡咯配合物的合成、性質及成像研究，2019.2-2021.1，已結題

5) 安徽師範大學博士啓動基金，2017XJJ28，肼橋聯吡咯類氟硼熒光染料的合成及性能研究，2017.5–2020.5，已結題

6) 國家自然科學基金青年基金項目，21402001，新型α,β位稠環Aza-BODIPY近紅外染料的合成及性能研究，2015.1–2017.12，已結題

1) Qian, W.; Wei, S.; Yu, C.;* Sun, Y.; Li, H.; Yu, T.; Zhang, H.;* Li, Y.;* Jiao, L.; Hao, E.* Solid-state emissive meso‐Aryl/Alkyl‐substituted and heteroatom-mixed BOPPY dyes: syntheses, structures, physicochemical, redox properties and computational analysis. Inorg. Chem. 2024, Accepted.

2) 孫營柱; 於長江;* 焦莉娟; 徐瑞明; 郝二紅;* 李家柱;* 劉鳴華. 苯並噻吩稠合雙硼熒光染料的手性光學性質及組裝手性放大研究. 《中國科學：化學》, 2024, Accepted

3) Sun, Y.; Yu, C.;* Qian, W.; Zhang, H.; Jiao, L.; Li, J.;* Liu, M.;* Hao, E.* Dynamically stable co-assembled supramolecular BOPPY systems with chiral amplification. Chem. Commun. 2023, 59, 13986. DOI: 10.1039/d3cc04727j.

4) Wang, X.; Fu, X.; Bu, W.; Yu, C.;* Hao, E.; Jiao, L.; Wu,* Q.; Wang, R.; Wang, J.; Li, J.* Bisbenzothieno[b]-fused BODIPYs as efficient near-infrared heavy-atom-free photosensitizers. Dyes Pigments 2023, 11591. DOI: 10.1016/j.dyepig.2023.111591.

5) Yu, C.;* Sun, Y.; Wu, Q.; Shi, Y.; Jiao, L.; Guo, X.; Li J.;* Li, J.;* Hao, E.* Synthesis, properties, and semiconducting characteristics of bisbenzothieno[b]-fused BODIPYs. J. Org. Chem. 2023, DOI: 1.01021/acs.joc.3c01186.

6) Zhao, X.; Hu, B.; Zhou, Q.; Yu, Y.; Hao, E.; Guo, X,; Xu, Y.;* Yu, C.;* Sun, K.;* Lalevée, J.* Triphenylamine-substituted BODIPY dye based photoinitiators for free radical and cationic photopolymerization under visible LED irradiation and application in 3D printing. Dyes Pigments 2023, 111880. DOI: 10.1016/j.dyepig.2023.111880.

7) Yu, C.;* Sun, Y.; Jiao, L.; Hao, E.* Recent advances of highly fluorescent hydrazine inserted pyrrole-based bisboron-anchoring fluorophores: Synthesis and properties. Syn. Lett. 2023, DOI: 10.1055/a-2045-2369.

8) Yu, C.;* Sun, Y.; Fang, X.; Li, J.;* Wu, Q.; Bu, W.; Guo, X.; Wang, H.; Jiao, L.; Hao, E.* Aromatic-ring-fused BOPPY fluorophores: Synthesis, spectral, redox properties, and bioimaging application. Inorg. Chem. 2022, 61, 16718. DOI: 10.1021/acs.inorgchem.2c02517.

9) Yu, C.;* Fang, X.; Wu, Q.; Chen, N.; Cheng, C.; Guo, X.; Hao, E.*; Jiao, L.* Synthesis and spectral properties of aggregation-induced emission-active push-pull chromophores based on isoindole scaffolds. Org. Lett. 2022, 24, 4557. DOI: 10.1021/acs.orglett.2c01659.

10) 於長江;* 程超; 郝二紅; 焦莉娟.* 芳並氮雜氟硼二吡咯的合成與應用. 《中國科學：化學》, 2022, 52, 1371. DOI: 10.1360/SSC-2022-0045.

11) Yu, C.;* Guo, X,; Fang, X.; Chen, Na; Wu, Q.; Hao, E.; Jiao, L.* Efficiently emissive, strongly slvatochromic and lipid droplet-specific, fluorescent probes for mapping polarity in vitro. Dyes Pigments 2022, 197, 109838. DOI: 10.1016/j.dyepig.2021.109838.

12) Yu, C.;* Fang, X.; Wang, H.; Guo, X,; Sun, L.; Wu, Q.; Jiao, L.; Hao, E.* A family of highly fluorescent and membrane-permeable bis(BF2) acyl-pyridinylhydrazine dyes with strong solid-state emission and large Stokes shifts: The BOAPH fluorophores. J. Org. Chem. 2021, 86, 11492.

13) Guo, X.; Tang, B.; Wu, H.; Wu, Q.; Xie, Z.; Yu, C.;* Hao, E.; Jiao, L.* Bright near-infrared a-tetraphenyletheneBODIPY nanoprobes with high aggregated state emission quantum yields in aqueous system for lipid droplet-specific imaging. Mater. Chem. Front. 2021, 5, 3664.

14) Zhao, Y.; Zhao, Y.; Yu, C.;* Liu, S.; Liu, Y.; Hao, E.;* Jiao, L.; Xu, X.; Zhang, Z.;* Li, J.* A novel family of non-symmetric benzothieno[7,6-b]-fused BODIPYs: Synthesis, structures, photophysical properties and lipid droplet-specific imaging in vitro. Dyes Pigments 2021, 196, 109748.

15) Yu, C.; Fang, X.; Wu, Q.; Jiao, L.*; Sun, L.; Li, Z.; So, P.-K.; Wong, W.-Y.*; Hao, E.* A family of BODIPY-like, highly fluorescent and unsymmetrical Bis(BF2) pyrrolyl-acylhydrazone chromophore: BOAPY, Org. Lett. 2020, 22, 4588

16) Wu, H.; Guo, X.; Yu, C.;* Wong, W.-Y.; Hao, E.; Jiao, L.* Highly photostable ketopyrrolyl-BODIPYs with red aggregation-induced emission characteristics for ultrafast wash-free mitochondria-targeted bioimaging. Dyes Pigments 2020, 176, 108209.

17) Yu, Y.; Yu, C.;* Wu, Q.; Wang, H.; Jiao, L.; Wong, W.-Y.; Hao, E.* Pure E/Z isomers of N-methylpyrrole-benzohydrazide-based BF2 complexes: Remarkable Aggregation-, crystallization-induced emission switching properties and application in sensing intracellular pH microenvironment. J. Mater. Chem. C 2019, 7, 4533.

18) Yu, C.; Hao, E.;* Fang, X.; Wu, Q.; Wang, L.; Li, J.; Xu, L.; Jiao, L.;* Wong, W.-Y.* AIE-active difluoroboronated acyl hydrazone dyes (BOAHY) emitting across the entire visible region and their photo-switching properties. J. Mater. Chem. C 2019, 7, 3269.

19) Yu, C.;+ Huang, Z.;+ Gu, W.; Wu, Q.; Hao, E.;* Xiao, Y.;* Jiao, L.;* Wong, W.-Y.* A novel family of AIE-active Meso-2-ketopyrrolylBODIPYs: Bright solid-state red fluorescence, morphological properties, and application as viscosimeters in live cells. Mater. Chem. Front. 2019, 3, 1823.

20) Yu, Y.; Yu, C.;* Wu, Q.; Wang, H.; Jiao, L.; Wong, W.-Y.; Hao, E.* Pure E/Z isomers of N-methylpyrrole-benzohydrazide-based BF2 complexes: Remarkable Aggregation-, crystallization-induced emission switching properties and application in sensing intracellular pH microenvironment. J. Mater. Chem. C 2019, 7, 4533.

21) Yu, C.; Huang, Z.; Wang, X.; Miao, W.; Wu, Q.; Wong, W.-Y.; Hao, E.;* Xiao, Y.;* Jiao L.* A family of highly fluorescent and unsymmetric Bis(BF2) chromophore containing both pyrrole and N-heteroarene derivatives: BOPPY. Org. Lett. 2018, 20, 4462. DOI: 10.1021/acs.orglett.8b01752

22) Yu, C.;* Li, T.; Wu, Q.; Hu, W.; Hao, E.; Jiao, L.* Synthesis structural and spectroscopic properties of quinoxaline-bridged bisBODIPYs. J. Porphyrins Phthalocyanines 2018, 22, 899.

23) Lv, X.; Li, T.; Wu, Q.; Yu, C.;* Jiao, L.; Hao, E.* Polybrominated BOPHY dyes: synthesis, reactivity, and properties. J. Org. Chem. 2018, 83, 1134.

24) Yu, C.;* Miao, W.; Wang, J.; Hao, E.; Jiao, L.* PyrrolylBODIPYs: syntheses, properties, and application as environment-sensitive fluorescence probes. ACS Omega 2017, 2, 3551.

25) Cui, J.; Sheng, W.; Wu, Q.; Yu, C.;* Hao, E.; Bobadova-Parvanova, P.;* Storer, M.; Asiri, A. M.; Marwani, H. M.; Jiao, L.* Synthesis, structure, and properties of near-infrared [b]phenanthrene-fused BF2 azadipyrromethenes. Chem. Asian J. 2017, 12, 2486. (Very Important Paper)

26) Yu, C.; Wu, Q.; Wang, J.; Wei, Y.; Hao, E.;* Jiao, L.* Red to near-infrared isoindole BODIPY fluorophores: synthesis, crystal structures, spectroscopic and electrochemical properties. J. Org. Chem. 2016, 81, 3761.

27) Yu, C.; Wu, Q.; Wang, J.; Tian, Z.; Hao, E.;* Jiao, L.* Synthesis and photophysical properties of meso-aryloxy linked BODIPY monomers, dimers, and trimer. J. Porphyrins Phthalocyanines 2016, 20, 475.

28) Li, T.; Gu, W.; Yu, C.;* Lv, X.; Wang, H.; Hao, E.; Jiao, L.* Syntheses and photophysical properties of meso-phenylene bridged boron dipyrromethene monomers, dimers and trimer. Chin. J. Chem. 2016, 34, 989.

29) Yu, C.; Jiao, L.;* Li, T.; Wu, Q.; Miao, W.; Wang, J.; Wei, Y.; Mu, X.; Hao, E.* Fusion and planarization of bisBODIPY: a new family of photostable near-infrared dyes. Chem. Commun. 2015, 51, 16852.

30) Yu, C.; Hao, E.;* Li, T.; Wang, J.; Sheng, W.; Wei, Y.; Mu, X.; Jiao, L.* Dipyrrolylquinoxaline difluoroborates with intense red solid-state fluorescence. Dalton Trans. 2015, 44, 13897. (Hot Article)

31) Yu, C.; Jiao, L.;* Zhang, P.; Feng, Z.; Cheng, C.; Wei, Y.; Mu, X. and Hao, E.* Highly fluorescent BF2 complexes of hydrazine-Schiff base linked bispyrrole, Org. Lett. 2014, 16, 3048.

32) Yu, C.; Jiao, L.; Hao, E. Research progress of functional modification of borondipyrromethene (BODIPY) fluorescent dyes. China Science paper 2013, 8, 1291. (in Chinese)

33) Yu, C.; Jiao, L.;* Tan, X.; Wang, J.; Xu, Y.; Wu, Y.; Yang, G.; Wang, Z.; Hao, E.* Straightforward acid-catalyzed synthesis of pyrrolyldipyrromethenes. Angew. Chem. Int. Ed. 2012, 51, 7688.

34) Yu, C.; Xu, Y.; Jiao, L.;* Zhou, J.; Wang, Z.; Hao, E.* Isoindole-BODIPY dyes as red to near-infrared fluorophores. Chem. Eur. J. 2012, 18, 6437.

35) Yu, C.; Jiao, L.;* Yin, H.; Zhou, Z.; Pang, W.; Wu, Y.; Wang, Z.; Yang, G.; Hao, E. α-/β-formylated borondipyrrin (BODIPY) dyes: regioselective syntheses and photophysical properties. Eur. J. Org. Chem. 2011, 28, 5460.

36) Jiao, L.;* Yu, C.; Wang, J.; Briggs, E. A.; Besley, A. L.; Robinson, D.; Ruedas-Rama, M. J.; Orte, A.; Crovetto, L.; Talavera, E. M.; Alvarez-Pez, J. M.; Van der Auweraer, M.; Boens, N. Unusual Spectroscopic and Photophysical Properties of meso-tert-ButylBODIPY in Comparison to Related Alkylated BODIPY Dyes. RSC Adv. 2015, 5, 89375.

37) Jiao, L.;* Yu, C.; Liu, M.; Wu, Y.; Cong, K.; Meng, T.; Wang, Y.; Hao, E. Synthesis and functionalization of asymmetrical benzo-fused BODIPY dyes. J. Org. Chem. 2010, 75, 6035.

38) Jiao, L.;* Yu, C.; Uppal, T.; Liu, M.; Li, Y.; Zhou, Y.; Hao, E.; Hu, X.; Vicente, M. G. H.* Long-wavelength red fluorescent dyes from 3,5-diiodo-BODIPYs. Org. Biomol. Chem. 2010, 8, 2517.

39) Jiao, L.;* Yu, C.; Li, J.; Wang, Z.; Wu, M.; Hao, E. β-FormylBODIPYs from Vilsmeyer-Haack Reaction. J. Org. Chem. 2009, 74, 7525.

40) Li, Z.; Zhang, L.; Wu, Q.; Li, H.; Kang, Z.; Yu, C.; Hao, E.*; Jiao, L.* Boron-Templated Synthesis of B(III)-Submonoazaporphyrins: The Hybrids of B(III)-Subporphyrins and B(III)-Subporphyrazines. J. Am. Chem. Soc. 2022, 144, 669

:

1) 於長江，郝二宏，焦莉娟，黃維揚，異吲哚四吡咯色素及其製備方法, 中國發明專利，授權專利號：ZL 201911273748.8.

2) 於長江，張子瑜，焦莉娟，郝二紅，苯並二吡咯酮氟硼熒光染料及其製備方法, 中國發明專利，授權專利號：ZL201911274610.X.

3) 於長江，郝二紅，焦莉娟，黃維揚，酰基吡啶肼雙氟硼強熒光染料及其製備方法, 中國發明專利，授權專利號：ZL201811258192.0.

4) 於長江，郝二紅，焦莉娟，黃維揚，meso-吡咯酮BODIPY染料粘度探針及其製備方法和應用, 中國發明專利，授權專利號：ZL201811258191.6.

5) 於長江，郝二紅，焦莉娟，黃維揚，吡咯吡啶肼雙氟硼熒光染料及其製備方法和應用，中國發明專利，授權專利號：ZL201810499299.8.

6) 黃維揚，於長江，雙異吲哚銥(III)配合物及其製備方法，中國發明專利，授權專利號：ZL202010160840.X.

7) 焦莉娟，於長江，吳昊，郝二紅，氟硼熒光探針在線粒體定位中的應用，中國發明專利，授權專利號：ZL202010039832.X.

8) 郝二紅，於長江，焦莉娟，黃維揚，線性共軛異吲哚多吡咯色素及其製備方法，中國發明專利，授權專利號：CN201911275827.2.

9) 郝二紅，於長江，張年榮，焦莉娟，一類吡咯腙肼雙氟硼熒光染料及其製備方法，中國發明專利，授權專利號：CN201810499260.6. ^[1]